So I was thinking how much I learned from watching other people's demos. You can seriously steal 'moves' from really good players.

With that said, I personally would be interested in having some of our pro players post footage of themselves playing. Who else would be interested? With enough support, I think we can pressure these players to letting out some of their secrets. Maybe I can also edit footage and put it into a playable movie if enough people are interested.
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Everyone knows about Daniel's 3-1 kill ratio and bla bla bla. That's all fun but I see what Daniel does differently as a demoman is avoid death very well. Also, he can be very effective on the defensive i.e. taking down 3 attackers once they are capturing the point, i.e. on Gravelpit or Well. These traits are really valuable on league-play and I'd like to see footage of this.
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This is not to alienate other players but just a tool for everyone to use.  We're all here to learn, right?